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5a+3=6a+8
We move all terms to the left:
5a+3-(6a+8)=0
We get rid of parentheses
5a-6a-8+3=0
We add all the numbers together, and all the variables
-1a-5=0
We move all terms containing a to the left, all other terms to the right
-a=5
a=5/-1
a=-5
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