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5.3a+14=77.6
We move all terms to the left:
5.3a+14-(77.6)=0
We add all the numbers together, and all the variables
5.3a-63.6=0
We move all terms containing a to the left, all other terms to the right
5.3a=63.6
a=63.6/5.3
a=12+7.105427357601E-15/5.3
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